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Ch 143: NMR Spectroscopy for Structural Identification
9.00 Credits
California Institute of Technology
This course will address both one-dimensional and two-dimensional techniques in NMR spectroscopy which are essential to elucidating structures of organic and organometallic samples. Dynamic NMR phenomena, multinuclear, paramagnetic and NOE effects will also be covered. An extensive survey of multipulse NMR methods will also contribute to a clear understanding of two-dimensional experiments. (Examples for Varian NMR instrumentation will be included.) Not offered 2012–13.
Prerequisite:
Ch 41 abc.
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Ch 144 ab: Advanced Organic Chemistry
9.00 Credits
California Institute of Technology
An advanced survey of selected topics in modern physical organic chemistry. Topics vary from year to year and may include structural and theoretical organic chemistry; molecular recognition/supramolecular chemistry; reaction mechanisms and the tools to study them; reactive intermediates; materials chemistry; pericyclic reactions; and photochemistry. Instructor: Dougherty (a). Part b not offered 2012–13.
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Ch 144 ab - Advanced Organic Chemistry
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Ch 145: Bioorganic Chemistry of Proteins
9.00 Credits
California Institute of Technology
An advanced survey of current and classic topics in bioorganic chemistry/chemical biology. The content will vary from year to year and may include the structure, function, and synthesis of peptides and proteins; enzyme catalysis and inhibition; carbohydrates and glycobiology; chemical genetics; genomics and proteomics; posttranslational modifications; chemical tools to study cellular dynamics; and enzyme evolution. Instructor: Hsieh-Wilson.
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Ch 145 - Bioorganic Chemistry of Proteins
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Ch 146: Bioorganic Chemistry of Nucleic Acids
9.00 Credits
California Institute of Technology
The course will examine the bioorganic chemistry of nucleic acids, including DNA and RNA structures, molecular recognition, and mechanistic analyses of covalent modification of nucleic acids. Topics include synthetic methods for the construction of DNA and RNA; separation techniques; recognition of duplex DNA by peptide analogs, proteins, and oligonucleotide-directed triple helical formation; RNA structure and RNA as catalysts (ribozymes). Not offered 2012–13.
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Ch 146 - Bioorganic Chemistry of Nucleic Acids
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Ch 147: Polymer Chemistry
9.00 Credits
California Institute of Technology
An introduction to the chemistry of polymers, including synthetic methods, mechanisms and kinetics of macromolecule formation, and characterization techniques. Not offered 2012–13.
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Ch 147 - Polymer Chemistry
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Ch 148: Polymer Physics
9.00 Credits
California Institute of Technology
An introduction to the physics that govern polymer structure and dynamics in liquid and solid states, and to the physical basis of characterization methods used in polymer science. The course emphasizes the scaling aspects of the various physical properties. Topics include conformation of a single polymer chain under different solvent conditions; dilute and semi-dilute solutions; thermodynamics of polymer blends and block copolymers; rubber elasticity; polymer gels; linear viscoelasticity of polymer solutions and melts; glass transition and crystallization. Given in alternate years; not offered 2012–13.
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Ch 148 - Polymer Physics
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Ch 15: Chemical Equilibrium and Analysis Laboratory
10.00 Credits
California Institute of Technology
Laboratory experiments are used to illustrate modern instrumental techniques that are currently employed in industrial and academic research. Emphasis is on determinations of chemical composition, measurement of equilibrium constants, evaluation of rates of chemical reactions, and trace-metal analysis. Instructor: Dalleska.
Prerequisite:
Ch 1 ab, Ch 3 a or Ch 3 x, Ch 14, or instructor’s permission.
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Ch 15 - Chemical Equilibrium and Analysis Laboratory
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Ch 153 ab: Advanced Inorganic Chemistry
9.00 Credits
California Institute of Technology
Ch 153 a: Topics in modern inorganic chemistry. Electronic structure, spectroscopy, and photochemistry with emphasis on examples from the modern research literature. Ch 153 b: Applications of physical methods toward the characterization of inorganic and bioinorganic species. A range of spectroscopic approaches will be covered. Instructors: Gray, Winkler (a); Peters (b).
Prerequisite:
Ch 112 and Ch 21 abc or concurrent registration.
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Ch 153 ab - Advanced Inorganic Chemistry
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Ch 154 ab: Organometallic Chemistry
9.00 Credits
California Institute of Technology
A general discussion of the reaction mechanisms and the synthetic and catalytic uses of transition metal organometallic compounds. Second term: a survey of the elementary reactions and methods for investigating reaction mechanisms. Third term: contemporary topics in inorganic and organometallic synthesis, structure and bonding, and applications in catalysis. Instructors: Bercaw. Part b not offered 2012–13.
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Ch 154 ab - Organometallic Chemistry
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Ch 155: Chemistry of Catalysis
9.00 Credits
California Institute of Technology
Discussion of homogeneous and heterogeneous catalytic reactions, with emphasis on the relationships between the two areas and their role in energy problems. Topics include catalysis by metals, metal oxides, zeolites, and soluble metal complexes; utilization of hydrocarbon resources; and catalytic applications in alternative energy approaches. Not offered 2012–13.
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Ch 155 - Chemistry of Catalysis
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