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Course Criteria
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1.00 Credits
Accompanies CHM U621. Complements and reinforces the concepts from CHM U621 with emphasis on fundamental techniques. Offers an opportunity to complete independent projects in modern chemical biology research.
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3.00 Credits
Surveys types of organic reactions including stereochemistry, influence of structure and medium, mechanistic aspects, and synthetic applications.
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3.00 Credits
Surveys tools used for elucidating mechanisms including thermodynamics, kinetics, solvent and isotope effects, and structure/reactivity relationships. Discusses olecular orbital theory, aromaticity, and orbital symmetry. Also explores reactive intermediates including carbenes, carbonium ions, radicals, biradicals and carbanions, acidity, and photochemistry.
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3.00 Credits
Determines organic structure based on proton and carbon nuclear magnetic resonance spectra, with additional information from mass and infrared spectra and elemental analysis. Presents descriptive theory of nuclear magnetic resonance experiments and applications of advanced techniques to structure determination. Includes relaxation, nuclear Overhauser effect, polarization transfer, and correlation in various one- and two-dimensional experiments.
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2.00 Credits
Determines the identity of unknown organic compounds by measurement of their physical constants, elemental analysis, preparation of derivatives, and spectroscopic methods (IR and NMR). The unknowns include single compounds, two- and three-component mixtures separable by extraction, and chromatography.
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3.00 Credits
Covers first law of thermodynamics, thermochemistry, second and third laws of thermodynamics, free energies, and reaction and phase equilibriums. Introduces the Boltzmann distribution, partition functions and their application to thermodynamics, and phase space. Applies statistical thermodynamics to selected physical systems.
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3.00 Credits
Covers the fundamentals of quantum mechanics, with applications to spectroscopy of atoms, molecules, and proteins. Topics include introduction to quantum mechanics; mathematical tools; rigid rotor; microwave spectroscopy; harmonic oscillator; infrared and Raman spectroscopy; hydrogen atom; emission spectra; electron spin; and applications to molecular and biological systems.
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3.00 Credits
Introduces molecular modeling methods that are basic tools in the study of macromolecules. Structured partly as a practical laboratory using a popular molecular modeling suite, and also aims to elucidate the underlying physical principles upon which molecular mechanics is based. These principles are presented in supplemental lectures or in laboratory workshops.
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3.00 Credits
Explores the use of experimental data to deduce the rate law of a reaction. Covers mechanisms deduced from rate laws, and the influence of experimental error on precision of rate constants and activation energies. Examines collision- and transition-state theories of reaction rates.
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3.00 Credits
Retired August 31, 2005. Offers an advanced undergraduate/introductory graduate course in inorganic chemistry. Topics include an introduction to solid-state structures and the origin of color in inorganic compounds. The synthesis, reactivity, and bonding of transition metal coordination compounds are described along with applications in health-related fields.
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